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How do I set the default email account for a user that has 2 POP3 accounts set up in Outlook 2000 so the FROM field in each email sent appears to be sent from XYZ instead of ABC?

It should be a similar option to Outlook 2003 below. But I can't find the equivalent in Outlook 2000.

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How to Set up Outlook 2000 Accounts

You can find the button in the "Internet Accounts" dialog in the "Tools" menu -> "Accounts":

Internet Accounts Dialog

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I only have "Services" available under the Tools menu, and that button doesn't appear to be listed anywhere – SuperFurryToad Jul 29 '10 at 11:27
up vote 0 down vote accepted

In the end, I solved the problem by starting over and re-creating the user's Outlook profile

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