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When sending an email to someone in Outlook it remembers their address, so if you try and send another email to them it'll prompt you with it - even if you haven't added them to the address book.

Is there any way of exporting those remembered addresses, or saving them to the address book?

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Utilities not really necessary, it is simply a single file See this explanation for details

You only need to know the user name and the name of the associated pst file.

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up vote 1 down vote accepted

Ahh, since asking the question I've found they're referred to as auto-complete nicknames, and a number of utilities exist for migrating:

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