The TrueCrypt authors explicitly recommend not doing this. When you copy a container, all copies share the same master-key. While this doesn't allow an attacker to break the encryption itself, it leaks some information.
If you follow the above steps, you will help prevent adversaries from finding out:
Which sectors of the volumes are changing (because you always follow step 1). This is particularly important, for example, if you store the backup volume on a device kept in a bank's safe deposit box (or in any other location that an adversary can repeatedly access) and the volume contains a hidden volume (for more information, see the subsection Security Requirements and Precautions Pertaining to Hidden Volumes in the chapter Plausible Deniability).
From http://www.truecrypt.org/docs/?s=how-to-back-up-securely
And of course you can forget about plausible deniability if you use multiple containers with the same master key.