If i am connected to the company VPN from home using my home PC, but i did not log into remote desktop to connect to my office computer. Can my company still see what pages i have surf using my home computer & ISP?
If your Internet connection passes through your company, then it can certainly monitor what you are doing.
But if your Internet connection goes directly from your home to your ISP, then the company is not involved.
The simplest way to verify where you are getting your Internet while connected to the VPN, is to go on What Is My IP Address, click on the left on "IP Address Lookup", then click on the button Lookup. If the address you see is not that of your home neighborhood, then your Internet connection is through the company. Of course, this only works if your home and company do not get your Internet from the same ISP and are situated in the same neighborhood (leave me a comment in this case).
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If you have left the default option of use default gateway, then yes your traffic goes through the company. If you're just on the company vpn and its configured to use company dns servers, then yes, they could find out what sites you're going to by looking through the logs.