See the command-line route utility. You will want to use route add to create an entry that tells all LAN traffic destined for the other PC to go through your Ethernet interface.
Syntax example:
> route ADD 192.168.0.99 MASK 255.255.255.0 192.168.0.254 METRIC 3 IF 2
destination^ ^mask ^gateway metric^ ^
Interface^
you can get the interface number by running a route print.
C:\Users\John>route print
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Interface List
16...00 1f 3a fd 8c 64 ......Bluetooth Device (Personal Area Network)
12...00 1d e0 b2 98 db ......Intel(R) Wireless WiFi Link
11...00 1e 37 88 e1 62 ......Intel(R) Gigabit Network Connection
19...08 00 27 00 e4 f7 ......VirtualBox Host-Only Ethernet Adapter
1...........................Software Loopback Interface 1
22...00 00 00 00 00 00 00 e0 Microsoft ISATAP Adapter
13...00 00 00 00 00 00 00 e0 Teredo Tunneling Pseudo-Interface
33...00 00 00 00 00 00 00 e0 Microsoft ISATAP Adapter #2
14...00 00 00 00 00 00 00 e0 Microsoft 6to4 Adapter
20...00 00 00 00 00 00 00 e0 Microsoft ISATAP Adapter #4
34...00 00 00 00 00 00 00 e0 Microsoft ISATAP Adapter #3
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