I am trying to understand how to convert WMV to ASF file using either ffmpeg or Expression encoder application.
Couldn't really figure out how to achieve that.
Thank you in advance.
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ASF and WMV are one and the same - ASF stands for Advanced Systems Format which is the container format used by WMV video files (and WMA audio files), so ASF files that contain video usually have a WMV extension.
Having said that you do not any conversion since there is only one format in your question ;-)