I have multiple accounts I access in Outlook, I would like to automatically add a signature to one of them (not the default one). Normally to send an email from one of the other accounts I click new email, then change the from account, however that doesn't add the associated signature. How does one accomplish this?
Insert a signature automatically
Insert a signature manually
Edit: Provided you have assigned a signature to the currently selected account, Outlook 2010 will change the signature when you select a different account from the Account dropdown. So make sure each account has a default signature set for this to work, even if the signature is blank.
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2 years later I was faced with the same issue. The solution is to add the second mailbox as an "E-mail Account" and not as an "Additional Mailbox" of the default mailbox. Seems that it would work either way but it doesn't.