In 'moving' from one machine to another, I have backed up desktop, my documents, and .pst files. Am I missing anything significant, considering the user only really used Office and the browser?
For moving user account from one computer to another I use User Profile Wizard 3.0 and it works great. IT moves all documents,setting for your application if you want, explorer settings, start menu, ... and is simple. I used it many times without problem when migrating desktops to domain.