In an ACL (Access control list) you can give allow ACEs (Access control entry) and deny ACEs. Deny ACEs have precedence over allow ACEs. So if you added deny Access for Administrators and you are a member of the Administrators Group, then that deny entry overrides the allow entry for your user. When you changed the file access rights in Explorer, Explorer gave you a warning stating exactly that. You dismissed that warning, now you got a problem.
If there is an account that is not in the Administrators group and is allowed to change file access on that file, then that user can remove the deny ACE. If there is no user, then you might have success setting back the computer to a restore point or connecting the hard drive to another computer and change the access rights there. Who is the owner of the file? File owners normally have some implicit additional rights, maybe the file owner can change the ACL?