Most motherboards have both the 3pin and 2pin power LED header, I'd be surprised if yours actually didn't. Since you didn't supply you motherboard's model number I can't confirm or deny that for you; check your manual.
If it doesn't, just use an X-acto knife with a fine point on it to gently pry the plastic tabs back, while gently pulling/tugging the wire, to release the wire's metal end from the plastic housing.
Then push it into the middle hole and it should click back in (if you were careful enough when removing it :) ).
You now have the two wires right next to each other, suitable for plugging into a 2-pin header. If the now-empty 3rd hole is in the way fro some reason, just trim it off with a pair of side-cutters.