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This question already has an answer here:

How do I prevent Windows Mobile Device Center from opening when I connect a Pocket PC device to a Windows 7 computer? Is this behaving like ActiveSync on Windows XP?

marked as duplicate by Ƭᴇcʜιᴇ007, Scott, afrazier, Nifle, Brad Patton May 12 '13 at 12:30

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See: Prevent Mobile Device Center from launching when connecting a device in Windows 7

The short answer seems to be kill the WMDC.exe process.

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