According to this TechNet discussion it is not possible to require two factors for logon using Windows Hello (the logon service for biometrics on Windows) on standalone systems (outside of Active Directory). Factors are all either/or such as fingerprint or PIN.
It might be possible to do this with third party software if it installs itself as a GINA DLL and can read the biometric or other factor and requires a PIN in addition. I'm unsure though if Windows 10 still supports alternative logons via GINA DLLs. You would also need to find a third party GINA DLL program which was able to read your second factor and had the option to require a pin in addition.
There is a third party GINA DLL provider which is open source and may be able to be made to meet your needs called pGINA but it is unclear whether it will work in Windows 10 or is still being actively developed.