The Safely Remove Hardware icon in Windows 8 (and 8.1) offers the ability to eject my internal SATA drives, including the boot drive (see example):
I don't see myself ever needing this - especially not from the convenience of the tray icon.
For Windows 7 exists well known solution (answer 1, answer 2, etc). But in Windows 8 msahci driver has been replaced by storahci. Unfortunately, TreatAsInternalPort workaround no longer works.